Research Contributions:
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Laser material processing at two contrasting forefronts—extremely short wavelength lasers and ultrafast
lasers—have been studied and applied to emerging new fields in photonics, biophotonic devices, electronics,
and micro-electro-mechanical structures (MEMs).
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Vacuum-Ultraviolet Laser Processing of Materials - F2 Laser:
Our laboratory has pioneered the development of several novel materials processing applications
centred on the 157-nm fluorine laser. The work was born out of collaboration with Lumonics, Canada
in the early 1990’s, in which we developed a high-energy vacuum-ultraviolet (VUV) laser. Our group
showed that the short-wavelength light furnishes smooth surfaces, supports nano-scale surface
structuring (~100 nm), and offers precise etch-depth control (<25 nm), for microfabrication
applications of novel electronic, biomedical and photonic components. The unique processing facility
also cultivates many opportunities for scientific collaborations around the world. We worked with
G. Mourou and X. Liu (Center for Ultrafast Optical Sciences, University of Michigan) to extend our
VUV technique of profiling rib waveguides to ultrafast lasers, and are continuing this work with
Prof. Marjoribanks, Miller, and Nantel at the University of Toronto. We are currently working with
G. Marowsky and J. Ihlemann of Laser Laboratorium, Goettingen (Germany) to micropattern dielectric
masks and binary optical components. F2-laser
poling is also being studied here with S. Fleming and T. Xu of the Optical Fibre Technology Centre
in Australia.
Our research work has been influential in stimulating related research in Japan and Germany, home
to world leaders in laser materials processing research and manufacturing. Our silica work inspired
Prof. Jitsuno of the Institute of Laser Engineering to apply F2
lasers to directly shape large lenses for aberration correction. Lambda Physik was encoraged to
establish a F2 laser micromachining
facility in Florida. International research groups and industry scientists frequently tour our
laboratory: our group hosted three long-term visitors funded by Japan: Prof. K. Kurosawa (Miyazaki
University), H. Higaki (Kyoto U.), and H. Yamakoshi (Mitsubishi Heavy Industries), several short-term
visitors, and numerous industry-group tours. Our laser processing developments, especially in photonics
microfabrication, has attracted widespread industrial interest, cooperation, and research support.
Lambda Physik and partner MicroLas provided strong support towards commercial exploitation of
F2-laser technology for processing photonic
materials. We have begun prototype work with several companies (JDS Uniphase, Scintrex,
Raytheon - Elcan Optical Technologies, Photonics Integrated Research). This success convinced
the Canadian Foundation for Innovation to strengthen our F2-
laser processing program with $ 1.6M (combined total) over 3 years. Industrial interactions are strong
and very active (Section 4)—near term commercialization is anticipated, possibly through a start-up company.
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F2
Laser Characterization:
Our measurement of a surprisingly
narrow linewidth (5 pm) suggested several possible coherent VUV applications
such as the fabrication of 0.11-mm period surface-relief gratings and stimulated
our subsequent work on writing photonic structures (Bragg gratings) in
glass. This narrow linewidth is of
current importance to semiconductor lithography now that Sematech (www.sematech.org) has placed
the F2 laser on the roadmap.
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Glass Photosensitivity at 157-nm Wavelength:
The potential impact
of our current photosensitivity studies is exceptionally promising. We
are pioneering basic science studies at this record short wavelength and
are attracting industrial interest because of the rapid refractive index
changes driven by this radiation. The
shorter wavelength extends practical index writing to ‘pure’ fused silica,
a material which does not respond materially at longer wavelengths.
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Intense
Ps-Laser Interaction with Nanostructured Surfaces:
A
three-way collaboration was stimulated with Prof. M. Moskovits (Chemistry)
and Marjoribanks (Physics) to investigate the soft x-ray conversion efficiency
of a new type of structured surface—a ‘nanowire’ target. The
velvet-like “black” structure is fundamentally interesting for studying
plasma closure on 1-ps time scales and the dependence of absorption on
laser polarization. Of practical
importance is the order-of-magnitude increase in the soft x-ray yield for
efficient photopumping of EUV lasers.
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Deep-Ultraviolet Vs. Ultrafast Laser
Processing:
A 12-year collaboration with Prof. R. Marjoribanks (Physics, University of Toronto)
provided an exciting base of studies in laser-matter interaction physics, and in comparing
deep-ultraviolet laser processing with ultrafast lasers. We discovered that pondermotive
effects provide a 10-fold enhancement of 1-ps laser etch rate. We defined ultrafast-laser
processing windows for micromachining transparent glasses and metal foils, and provided
head-to-head comparison with F2-laser
results. This latter work was influential in taming overzealous claims amongst ultrafast laser
research groups on the merits of such lasers, and many other groups now follow a similar
comparison style. A collaboration with Dr. P. Corkum (National Research Council, Canada)
is pointing to interesting contrasts of deep-ultraviolet and ultrafast lasers in writing
refractive-index structures in glasses – the photosensitivity response was surprisingly
similar for different underlying interactions of single photon vs. multi-photon absorption.
Our group is extending this waveguiding writing effort to the patterning of three-dimensional
photonic structures. Joint modeling efforts with Prof. J. Sipe (Physics, University of Toronto)
promise to create new photonic component designs that serve the heart of today’s rapidly expanding
optical communication networks.
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Burst-Ultrafast Laser MicroFabrication
With Prof. Marjoribanks, we discovered a new mode of laser interaction that combines the
attributes of ultrafast laser processing with the smoothing benefit of a thermal process.
Rapid bursts (133 MHz) of 1-ps pulses provided ‘crack-free’ micromachining of glasses –
overcoming a real limitation with conventional ultrafast laser systems. A patent application
is in progress. Our work motivated Prof. Mazur’s group (Harvard University) to rebuild their
ultrafast laser oscillator and extend burst-processing to optical waveguide writing. Work
with Dr. P. Corkum suggests a 3-fold photosensitivity enhancement due to a burst-driven
thermal process. Our current research is expanding the scope of these studies to broader
range of materials; rapid formation of photonic circuits is an especially promising research area.
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Laser-Induced Breakdown Spectroscopy (LIBS):
Our group is exploring with Alcan International, novel laser approaches that can provide accurate assays of aluminum for sorting scrap metal in automobile recycling plans. The technique of laser-induced optical emission spectroscopy (OES) is being studied with various laser approaches - infrared and ultraviolet wavelength sources, shaped pulses, and bursts of ultrafast light - to optimize the precision and the speed of the diagnostic process. A viable laser-based automobile recycling system is required within the next 3 to 5 years to reduce to recovery cost of high-grade aluminum alloys from automobiles. This effort will encourage more use of light-weight metal in automobiles and help reduce fuel consumption.
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Laser
Processing Facilities:
The above work has stimulated numerous collaborations with new and existing
colleagues at the University of Toronto, that has over the years built
a critical mass of research activity in laser processing. Laser
processing is now one key theme area in the provincial centre of excellence,
Photonics Research Ontario. Collective
efforts have brought much increased research funding, established state-of-the-art
research facilities, and developed a broad range of expertise from laser
physics to material diagnostics to support advanced laser-processing research
and training at the University of Toronto.
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